Product ID:ANHYDROL SOLVENT SPECIAL/PM 4079/190 PROOF
MSDS Date:12/07/1990
FSC:6850
NIIN:00F013230
MSDS Number: BJHKK

UNION CARBIDE CHEM. & PLASTICS CO INC

39 OLD RIDGEBURY RD
DANBURY, CT 06817-0001
US

Emergency Phone: 203-794-6753

Info Phone: 800-822-4357

Cage: 0TAZ2

UNION CARBIDE CORPORATION

DANBURY, CT 06817-0001 US

Telephone: 1-800-568-4000 / 732-563-5522

Cage: 0TAZ2

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 79.6%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 13%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ISOBUTYL KETONE (SARA III)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 0.9%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

WATER, H2O

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 6.5%

ACETALDEHYDE (GROUP 2B CARCINOGEN BY IARC, SUSPECTED

CAS: 75-07-0

RTECS: AB1925000

Fraction By Weight: >1%

OSHA PEL 360 MG/CUM

ACGIH TLV: 180 MG/CUM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

802 G/L

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: MINOR IRRITATION. VISUAL EFFECTS
INCLUDE: DIPLOPIA, COMPLETE BLINDNESS. METHANOL PRODUCES ACIDOSIS.
INGESTION: DEATH. SKIN: ABSORPTION OF HARMFUL AMOUNT OF METHANOL.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:NAUSEA, ABDOMINAL PAIN, VOMITING, HEADAHCE,
SHORTNESS OF BREATH, DRUNKEN BEHAVIOR, VISUAL DISTURBANCES,
DROWSINESS, BLURRED VISION, RESTRICTION OF VISUAL FIELDS,
REDDENING., IRRITATION, COMA.

First Aid:INGESTION: GIVE 2 GLASSES OF WATER & INDUCE VOMITING. NEVER
MAKE AN UNCONSCIOUS PERSON VOMIT/TAKE ANYTHING BY MOUTH. IF
DELAYED, SWALLOWED A FEW OUNCES MORE, GIVE 3-4 OUNCES OF HARD
LIQUOR. SKIN/EYES: FLUSH W/WATER. INHALATION: REMOVE TO FRESH AIR.
OBTAIN MEDICAL ATTENTION IN ALL CASES. (SEE SUPP)

Flash Point Method:TCC
Flash Point:60F
Lower Limits:SUPP
Upper Limits:SUPP
Extinguishing Media:SMALL: CO2, DRY CHEMICAL. LARGE: ALCOHOL/ALL
PURPOSE TYPE FOAMS
Fire Fighting Procedures:USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS & STRUCTURES. USE SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING. USE WATER SPRAY TO DISPERSE VAPORS.
Unusual Fire/Explosion Hazard:VAPORS MAY SETTLE IN LOW/CONFINED
AREAS/TRAVEL/MOVED BY AIR CURRENTS DISTANT FROM HANDLING POINT &
FLASH BACK EXPLOSIVELY. MAY PRODUCE A FLOATING FIRE HAZARD.

Spill Release Procedures:EXTINGUISH & DON'T TURN ON ANY IGNITION
SOURCES. WEAR SUITABLE PROTECTIVE EQUIPMENT. LARGE: COLLECT FOR
DISPOSAL. SMALL: FLUSH W/WATER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, & FLAME.
AVOID BREATHING VAPORS. KEEP CONTAINER CLOSED. USE W/ADEQUATE
VENTILATION. DON'T TAKE INTERNALLY.
Other Precautions:FOR INDUSTRIAL USE ONLY. STORE AT NORMAL AMBIENT
TEMPERATURES.

Respiratory Protection:SELF-CONTAINED BREATHING APPARATUS IN HIGH VAPOR
CONCENTRATIONS
Ventilation:MECHANICAL (GENERAL); LOCAL
Protective Gloves:NEOPRENE/POLYVINYL CHLORINATED
Eye Protection:SAFETY GLASSES
Other Protective Equipment:EYE BATH, SAFETY SHOWER, CHEMICAL APRON
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
LOWER EXPLOSIVE LIMIT (ETHANOL): 3.3. UPPER EXPLOSIVE LIMIT (THANOL):
19. NOTE TO PHYSICIAN: DUE TO MAJOR TOXICITY, TREATMENT SHOULD
INCLUDE: HEMODIALYSIS, INTRAVENOUS ADMINISTRATION OF ETHANOL TO INT
ERFERE W/METABOLISM OF METHYL ALCOHOL &ADMINISTRATION OF SODIUM
BICARBONATE TO CORRECT ACIDOSIS.

Boiling Pt:B.P. Text:172F
Melt/Freeze Pt:M.P/F.P Text:<-130F
Vapor Pres:45
Vapor Density:1.4
Spec Gravity:0.81
Evaporation Rate & Reference:(BU AC =1): 3.2
Solubility in Water:COMPLETE
Appearance and Odor:WATER, WHITE LIQUID W/NONRESIDUAL ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
CONCENTRATED NITRIC & SULFURIC ACIDS, STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, SPARKS, FLAMES, ELECTRICAL
EQUIPMENT, STATIC DISCHARGES, & IGNITION SOURCES
Hazardous Decomposition Products:CO, CO2

Waste Disposal Methods:INCINERATE IN A FURNACE WHERE PERMITTED UNDER
APPROPRIATE FEDERAL, STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.